Ethylene glycol monobenzoate → 2-Benzoyloxyethyl 12-acetoxyoleate

HRID 2398106Notes

Reaction equation

HRID 2398106 reaction equation
[C:1]([O:9][CH2:10][CH2:11][OH:12])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:13]([O:16][CH:17]([CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH3:36])[CH2:18]/[CH:19]=[CH:20]\[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][C:28](Cl)=[O:29])(=[O:15])[CH3:14]>>[C:13]([O:16][CH:17]([CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH3:36])[CH2:18]/[CH:19]=[CH:20]\[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][C:28]([O:12][CH2:11][CH2:10][O:9][C:1](=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)=[O:29])(=[O:15])[CH3:14]

Participants

3

Reactant 2

HCID 66747Ethylene glycol monobenzoateHCID 8673475912-Acetoxyoleoyl chloride

Product 1

HCID 679349392-Benzoyloxyethyl 12-acetoxyoleate

Procedure

2-Benzoyloxyethyl 12-acetoxyoleate was prepared by the procedure of Example 1 from 16 gms (0.1 mole) of ethylene glycol monobenzoate and 36 gms (0.1 mole) of 12-acetoxyoleoyl chloride. The structure of the final product was characterized on the basis of NMR and IR spectral analyses as described in Example 1.

Sources & evidence

ORD record
ord-7b2f5c37bc0544a4a4f483f65e83c074
Source dataset
uspto-grants-1977_05
Patent number
US04024164

Reaction notes

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