Diethylene glycol monobenzoate → Benzoyloxyethoxyethyl 12-acetoxy-oleate

HRID 2398108Notes

Reaction equation

HRID 2398108 reaction equation
[C:1]([O:9][CH2:10][CH2:11][O:12][CH2:13][CH2:14][OH:15])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:16]([O:19][CH:20]([CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39])[CH2:21]/[CH:22]=[CH:23]\[CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][C:31](Cl)=[O:32])(=[O:18])[CH3:17]>>[C:16]([O:19][CH:20]([CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39])[CH2:21]/[CH:22]=[CH:23]\[CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][C:31]([O:15][CH2:14][CH2:13][O:12][CH2:11][CH2:10][O:9][C:1](=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)=[O:32])(=[O:18])[CH3:17]

Participants

3

Reactant 2

HCID 88603Diethylene glycol monobenzoateHCID 8673475912-Acetoxyoleoyl chloride

Product 1

HCID 70620795Benzoyloxyethoxyethyl 12-acetoxy-oleate

Procedure

2-Benzoyloxyethoxyethyl 12-acetoxyoleate was prepared by the procedure of Example 1 from 21 gms (0.1 mole) of diethylene glycol monobenzoate and 36 gms (0.1 mole) of 12-acetoxyoleoyl chloride. The structure of the final product was characterized on the basis of NMR and IR spectral analyses as described in Example 1.

Sources & evidence

ORD record
ord-17712984deac44d9910f1386ceb3afc5
Source dataset
uspto-grants-1977_05
Patent number
US04024164

Reaction notes

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