Pivaloyl chloride → 4-Benzoyloxy-2-butenyl trimethylacetate

HRID 2398112Notes

Reaction equation

[C:1]([O:9][CH2:10][CH:11]=[CH:12][CH2:13][OH:14])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH3:15][C:16]([CH3:21])([CH3:20])[C:17](Cl)=[O:18]>>[CH3:15][C:16]([CH3:21])([CH3:20])[C:17]([O:14][CH2:13][CH:12]=[CH:11][CH2:10][O:9][C:1](=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)=[O:18]

Participants

Reactant 2

HCID 62493Pivaloyl chloride

HCID 541501864-Hydroxybut-2-enyl benzoate

Product 1

HCID 3216944-Benzoyloxy-2-butenyl trimethylacetate

Procedure

4-Benzoyloxy-2-butenyl trimethylacetate was prepared by the procedure of Example 1 from 19 gms (0.1 mole) of 4-hydroxy-2-butenyl benzoate and 12 gms (0.1 mole) of trimethylacetyl chloride. The structure of the final product was characterized on the basis of NMR and IR spectral analyses as described in Example 1.

Sources & evidence

ORD record: ord-d2c992d7e0c34a31ba7235ca8b4432da
Source dataset: uspto-grants-1977_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04024164

Reaction notes

Loading…