HuagongsheHuagongshe Chemistry Print Report · For research reference only
Cyclooctylamine → HCID 4722991, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Cyclooctylamine | HCID 2903 | — |
| Reactant | p-Toluenesulfonic acid | HCID 6101 | — |
| Reactant | Piperonal | HCID 8438 | — |
| Catalyst | Nickel | HCID 935 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | HCID 4722991 | HCID 4722991 | — |
Reaction Steps
16.5 g of piperonal, 12,7a g of cyclooctylamine and a catalytical amount of p-toluene-sulfonic acid were hydrogenated for 6 hours in 500 ml of methanol over Raney nickel at 100° C/100 atmospheres gauge pressure. After removal of the catalyst, evaporation of the solution and treatment of the residue with methanolic HCl, there were obtained 23 g of N-cyclooctyl-3,4-methylenedioxy-benzylamine. Melting point 164°-165° C (from ethanol/ether).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04024274 |
| Source dataset | uspto-grants-1977_05 |
| ORD ID | ord-f01a8a3298514ec4ae5402dacdae5b5f |
| Source note | uspto-grants-1977_05 |