HCID 21432960, compound → HCID 21432958, compound

HRID 2398520Notes

Reaction equation

HRID 2398520 reaction equation
[C:1]([CH2:3][CH2:4][O:5][P:6]([CH2:9][NH:10][CH2:11][C:12]([O:14]CC)=[O:13])([OH:8])=[O:7])#[N:2]>O>[C:1]([CH2:3][CH2:4][O:5][P:6]([CH2:9][NH:10][CH2:11][C:12]([OH:14])=[O:13])([OH:8])=[O:7])#[N:2]

Participants

3

Reactant 1

HCID 21432960HCID 21432960, compound

Product 1

HCID 21432958HCID 21432958, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

25 g (0.1 mols) of ethyl N-[O-(β-cyanoethyl)-phosphonomethyl]-aminoacetate in 200 ml of water are heated under reflux for 16 hours. The water is then evaporated off in vacuo in a rotary evaporator and the residue is dried at 50° under high vacuum. Thereafter the residue is warmed with 300 ml of ethanol.

Workup

  1. temperatureunder reflux for 16 hours
  2. customThe water is then evaporated off in vacuo in a rotary evaporator
  3. customthe residue is dried at 50° under high vacuum
  4. temperatureThereafter the residue is warmed with 300 ml of ethanol

Sources & evidence

ORD record
ord-95113e0a13cc4c06b23ccbdf92051cb6
Source dataset
uspto-grants-1977_05
Patent number
US04025331

Reaction notes

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