Methyl iodide → HCID 22761648, compound

HRID 2398558Notes

Reaction equation

HRID 2398558 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([N:10]2[C:14](=[O:15])[C:13]3=[CH:16][C:17]([Cl:20])=[CH:18][CH:19]=[C:12]3[C:11]2=[O:21])=[C:6]([CH2:22]SC)[CH:5]=1)([O-:3])=[O:2].C[I:26]>>[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([N:10]2[C:14](=[O:15])[C:13]3=[CH:16][C:17]([Cl:20])=[CH:18][CH:19]=[C:12]3[C:11]2=[O:21])=[C:6]([CH2:22][I:26])[CH:5]=1)([O-:3])=[O:2]

Participants

3

Reactant 2

HCID 6328Methyl iodideHCID 54283452HCID 54283452, compound

Product 1

HCID 22761648HCID 22761648, compound

Procedure

The mixture of 1.5 g of N-(4-nitro-2-methylmercaptomethylphenyl)-4-chlorophthalimide and 50 ml of methyl iodide is refluxed for 6 days in the absence of light and evaporated. The residue is taken up in hot benzene, the mixture filtered and evaporated to yield the N-(4-nitro-2-iodomethylphenyl)-4-chlorophthalimide melting at 183°-187°.

Workup

  1. temperatureis refluxed for 6 days in the absence of light
  2. customevaporated
  3. filtrationthe mixture filtered
  4. customevaporated

Sources & evidence

ORD record
ord-79072fc1eb16422a856285151731f2c5
Source dataset
uspto-grants-1977_05
Patent number
US04025505

Reaction notes

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