反应详情

A solution of 9.6 g (0.05 mole) of 5-chloro-3-methyl-1-phenylpyrazole and 25 ml of acetic anhydride was added at 10° C. to a solution of acetyl nitrate prepared from 25 ml of 90% nitric acid and 10 ml of acetic anhydride. The solution was stirred 2 hours at 20°-30° C. and carefully poured onto ice water. The solid was filtered off and washed with cold water. One recrystallization from ethanol gave long white needles of product.

1. additioncarefully poured onto ice water
2. filtrationThe solid was filtered off
3. washwashed with cold water
4. customOne recrystallization from ethanol
5. customgave long white needles of product