HCID 21433374, compound → HCID 86734768, compound

HRID 2398633Notes

Reaction equation

HRID 2398633 reaction equation
Br[C:2]1[CH:15]=[CH:14][C:5]([NH:6][C:7](=[S:13])[S:8][CH2:9][C:10](Cl)=[CH2:11])=[C:4]([CH3:16])[CH:3]=1.[Br:17]C1C=CC(NC(=S)[S-])=C(C)C=1.C([NH+](CC)CC)C>>[Br:17][C:15]1[CH:2]=[CH:3][C:4]([CH3:16])=[C:5]([N:6]=[C:7]2[S:13][C:10]([CH3:11])=[CH:9][S:8]2)[CH:14]=1

Participants

3

Reactant 2

HCID 21433374HCID 21433374, compoundHCID 21433377HCID 21433377, compound

Product 1

HCID 86734768HCID 86734768, compound

Procedure

By the procedure of Example 1, 2-chloroallyl 4-bromo-2-methyldithiocarbanilate is prepared substituting triethylammonium 4-bromo-2-methyldithiocarbanilate for the 4-chloro derivative of the same and cyclized as in Example 1 to yield 2-(4-bromo-o-tolyl)imino-4-methyl-1,3-dithiole in good yield and purity.

Sources & evidence

ORD record
ord-51c8237592b1461588cd8d88ea5fe25b
Source dataset
uspto-grants-1977_05
Patent number
US04025532

Reaction notes

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