HuagongsheHuagongshe Chemistry Print Report · For research reference only
N-bromobutanimide → 3-Furancarboxylic acid, 2,5-dimethyl-, ethyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | Ethyl 2-acetyl-2-pentenoate | HCID 54249081 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | 3-Furancarboxylic acid, 2,5-dimethyl-, ethyl ester | HCID 141457 | 83.2% |
Reaction Steps
A mixture of 3.41 g (0.02 mole) ethyl 2-acetyl-2-pentenoate and 3.57 g (0.02 mole) N-bromosuccinimide in 50 ml of carbon tetrachloride was heated at reflux for 2 hours. After cooling, the succinimide was removed by filtration and the solution concentrated in vacuo. Distillation gave 2.8 g (83%) of ethyl 2,5-dimethyl-3-furoate, bp 96 °-100° C. (18 mm).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04025537 |
| Source dataset | uspto-grants-1977_05 |
| ORD ID | ord-67c5bc136b934568b8c409c5c2df7035 |
| Source note | uspto-grants-1977_05 |