HuagongsheHuagongshe Chemistry Print Report · For research reference only
N-bromobutanimide → HCID 21433410, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | 2-Decenoic acid, 2-acetyl-, ethyl ester | HCID 276516 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | HCID 21433410 | HCID 21433410 | 88.1% |
Reaction Steps
A mixture of 4.80 g (0.02 mole) ethyl 2-acetyl-2-decenoate and 3.56 g (0.02 mole) N-bromosuccinimide in 50 ml of carbon tetrachloride was heated at reflux for 12 hours. After cooling, the succinimide was removed by filtration and the solution concentrated by rotary evaporation. Distillation of the crude product gave 4.20 g (88%) of ethyl 5-hexyl-2-methyl-3-furoate, bp 107°-109° C. (0.4 mm).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04025537 |
| Source dataset | uspto-grants-1977_05 |
| ORD ID | ord-06460bb17f784183b5bd5beb99812f08 |
| Source note | uspto-grants-1977_05 |