HuagongsheHuagongshe Chemistry Print Report · For research reference only
N-bromobutanimide → HCID 12452846, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | 2,4-Pentanedione, 3-butylidene- | HCID 12210752 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | HCID 12452846 | HCID 12452846 | 99.9% |
Reaction Steps
A mixture of 3.56 g (0.02 mole) 3-acetyl-3-hepten-2-one and 3.55 g (0.02 mole) N-bromosuccinimide in 50 ml of carbon tetrachloride was heated at reflux for 2 hours. After cooling, the succinimide was removed by filtration and the solution concentrated in vacuo. Distillation of the crude product gave 3.04 g (86%) of 5-ethyl-2-methyl-3-furyl methyl ketone, bp 84°-87° C. (9 mm).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04025537 |
| Source dataset | uspto-grants-1977_05 |
| ORD ID | ord-7cd831d1510d42ebb0098177605073a5 |
| Source note | uspto-grants-1977_05 |