Carbon Disulfide → HCID 178433327, compound

HRID 2398674Notes

Reaction equation

HRID 2398674 reaction equation
[CH3:1][C:2]1[N:3]=[CH:4][NH:5][C:6]=1[CH2:7][S:8][CH2:9][CH2:10][NH2:11].[C:12](=[S:14])=[S:13]>C(O)C>[CH3:1][C:2]1[N:3]=[CH:4][NH:5][C:6]=1[CH2:7][S:8][CH2:9][CH2:10][NH:11][C:12](=[S:13])[SH:14]

Participants

4

Reactant 2

HCID 6348Carbon DisulfideHCID 178433288HCID 178433288, compound

Product 1

HCID 178433327HCID 178433327, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

(i) A solution of 4-methyl-5-((2-aminoethyl)thiomethyl)-imidazole (10.2 g.) in ethanol (75 ml.) was added slowly, with stirring, to carbon disulphide (200 ml.). The mixture was set aside overnight at room temperature and the solid formed was collected and recrystallized from aqueous isopropyl alcohol to afford N-[2-((4-methyl-5-imidazolyl)methylthio)ethyl]dithiocarbamic acid (9.8 g.), m.p. 127°-129°.

Workup

  1. customthe solid formed
  2. customwas collected
  3. customrecrystallized from aqueous isopropyl alcohol

Sources & evidence

ORD record
ord-85b90f1757234ec8a0c460b7a304ce15
Source dataset
uspto-grants-1977_05
Patent number
US04025527

Reaction notes

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