Acetone → HCID 20563853, compound

HRID 2398695Notes

Reaction equation

HRID 2398695 reaction equation
[Cl:1][C:2]1[C:3]([N+:16]([O-:18])=[O:17])=[C:4]([S:12](Cl)(=[O:14])=[O:13])[C:5]([CH3:11])=[CH:6][C:7]=1[N+:8]([O-:10])=[O:9].CC(C)=O.[NH3:23]>O>[Cl:1][C:2]1[C:3]([N+:16]([O-:18])=[O:17])=[C:4]([S:12]([NH2:23])(=[O:14])=[O:13])[C:5]([CH3:11])=[CH:6][C:7]=1[N+:8]([O-:10])=[O:9]

Participants

5

Reactant 3

HCID 180Acetone2×HCID 222AmmoniaHCID 20563848HCID 20563848, compound

Product 1

HCID 20563853HCID 20563853, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

4-Chloro-3,5-dinitro-o-toluenesulfonyl chloride (10 grams, 0.0318 mole) is dissolved in 150 ml. of acetone and chilled to -15° C. Ammonia (1.08 grams, 0.064 mole) is condensed and then vaporized into the acetone solution. When the addition is complete, the reaction mixture is poured into an equal volume of water and the precipitated solid collected. The crude yield of white solid is 6.8 grams with melting point 205° C. to 215° C.

Workup

  1. customcondensed
  2. additionWhen the addition
  3. customthe precipitated solid collected

Sources & evidence

ORD record
ord-11ad4cef373d4ecb8dbd3dedad7ada9f
Source dataset
uspto-grants-1977_05
Patent number
US04025538

Reaction notes

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