Carbon Tetrachloride → HCID 20384180, compound

HRID 2398770Notes

Reaction equation

HRID 2398770 reaction equation
[C:1]([C:4]1[CH:17]=[CH:16][C:15]2[O:14][C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[S:7](=[O:19])(=[O:18])[C:6]=2[CH:5]=1)([OH:3])=[O:2].[C:20](Cl)(Cl)(Cl)Cl>S(Cl)(Cl)=O>[CH3:20][O:2][C:1]([C:4]1[CH:17]=[CH:16][C:15]2[O:14][C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[S:7](=[O:19])(=[O:18])[C:6]=2[CH:5]=1)=[O:3]

Participants

4

Reactant 2

HCID 5943Carbon TetrachlorideHCID 15854266HCID 15854266, compound

Product 1

HCID 20384180HCID 20384180, compound

Reagents, catalysts & solvents 1

HCID 24386Thionyl ChlorideSolvent

Procedure

2-carboxyphenoxathiin-10,10-dioxide (0.50g.) in carbon tetrachloride (25ml.) and thionyl chloride (2.0 ml.) was boiled under reflux for 2 hr. The solvent was evaporated and methanol (20. ml.) added. The mixture was boiled under reflux for 20 min., and cooled, whereupon 2-methoxycarbonylphenoxathiin-10,10-dioxide crystallised out and was filtered off and dried, m.pt. 160° C.

Workup

  1. temperatureunder reflux for 2 hr
  2. customThe solvent was evaporated
  3. additionmethanol (20. ml.) added
  4. temperatureunder reflux for 20 min.
  5. temperaturecooled, whereupon 2-methoxycarbonylphenoxathiin-10,10-dioxide
  6. customcrystallised out
  7. filtrationwas filtered off
  8. customdried

Sources & evidence

ORD record
ord-84cda5c8fad64d8b9ff19ca8e5a929b7
Source dataset
uspto-grants-1977_05
Patent number
US04025635

Reaction notes

Loading…