HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → HCID 178527131, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | Ammonium Chloride | HCID 25517 | — |
| Reactant | Sodium Azide | HCID 33557 | — |
| Reactant | HCID 20384185 | HCID 20384185 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | HCID 178527131 | HCID 178527131 | — |
Reaction Steps
3-Cyanothianthrene-5,5-dioxide (0.55g), sodium azide (0.36g), ammonium chloride (0.30g) and dimethylformamide (15 ml) were heated together at 130°-135° C. for 3 hr. The mixture was cooled, poured into dilute hydrochloric acid, and the oily precipitated product extracted into chloroform and washed with water. On standing, 3-(5-tetrazolyl)thianthrene-5,5-dioxide crystallised out, m.p. 233° C. (decomposition).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04025635 |
| Source dataset | uspto-grants-1977_05 |
| ORD ID | ord-c022f0f2e03441328352c970e3efda84 |
| Source note | uspto-grants-1977_05 |