Methyl iodide → HCID 70546796, compound

HRID 2398837Notes

Reaction equation

HRID 2398837 reaction equation
[CH3:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([CH3:8])[C:3]=1[NH:9][C:10]([NH:12][C:13](=[O:19])[N:14]([CH2:17][CH3:18])[CH2:15][CH3:16])=[S:11].[I:20][CH3:21]>CO>[I-:20].[CH3:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([CH3:8])[C:3]=1[NH+:9]=[C:10]([NH:12][C:13](=[O:19])[N:14]([CH2:15][CH3:16])[CH2:17][CH3:18])[S:11][CH3:21]

Participants

4

Reactant 2

HCID 6328Methyl iodideHCID 21434161HCID 21434161, compound

Product 1

HCID 70546796HCID 70546796, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

(0.1 mole) of 1-(2,6-dimethylphenyl)-3-(N,N-diethylcarbamyl)thiourea is combined with 200 ml. of methanol and 14.1 g. (0.1 mole) of iodomethane and refluxed for 4 hours. This is then evaporated to dryness and 100 ml. of hexane is added. The mixture is filtered to obtain 1-(2,6-dimethylphenyl)-3-(N,N-diethylcarbamyl)-2-methylthiouronium iodide.

Workup

  1. customThis is then evaporated to dryness and 100 ml
  2. additionof hexane is added
  3. filtrationThe mixture is filtered

Sources & evidence

ORD record
ord-2ebe2fadc97847c4b2e0b3120ba55810
Source dataset
uspto-grants-1977_05
Patent number
US04025652

Reaction notes

Loading…