Acetone → HCID 14415665, compound

HRID 2399055Notes

Reaction equation

HRID 2399055 reaction equation
[CH3:1][C:2]1[C:3]([OH:11])=[C:4]([CH3:10])[C:5]([CH3:9])=[C:6]([CH:8]=1)[OH:7].[C:12]([C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)(=[O:15])[CH:13]=[CH2:14].[CH3:22]C(C)=O>>[OH:11][C:3]1[C:2]([CH3:1])=[C:8]2[C:6](=[C:5]([CH3:9])[C:4]=1[CH3:10])[O:7][C:12]([O:15][CH3:22])([C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)[CH2:13][CH2:14]2

Participants

4

Reactant 3

HCID 180AcetoneHCID 12785TrimethylhydroquinoneHCID 130281-Phenyl-2-propen-1-one

Product 1

HCID 14415665HCID 14415665, compound

Procedure

Trimethylhydroquinone was reacted with acrylophenone by the procedure of Example 1 to give (±)-6-hydroxy-2-methoxy-2-phenyl-5,7,8-trimethylchroman as a white solid, m.p. 190.5°-192.5° from acetone-30°-60° petroleum ether.

Sources & evidence

ORD record
ord-3bb797d87b3d4bcf8987149cc14f1c55
Source dataset
uspto-grants-1977_05
Patent number
US04026907

Reaction notes

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