Diethyl Ether → HCID 14415664, compound

HRID 2399056Notes

Reaction equation

[C:1]([C:5]1[CH:11]=[C:10]([OH:12])[CH:9]=[CH:8][C:6]=1[OH:7])([CH3:4])([CH3:3])[CH3:2].[CH:13]([C:15]([CH3:17])=[O:16])=[CH2:14].[CH3:18]COCC>>[C:1]([C:5]1[CH:11]=[C:10]2[C:9]([CH2:14][CH2:13][C:15]([O:16][CH3:18])([CH3:17])[O:12]2)=[CH:8][C:6]=1[OH:7])([CH3:4])([CH3:2])[CH3:3]

Participants

Reactant 3

HCID 3283Diethyl Ether

HCID 6570Methyl vinyl ketone

HCID 16043Tert-Butylhydroquinone

Product 1

HCID 14415664HCID 14415664, compound

Procedure

Reaction of tert-butyl-hydroquinone with methyl vinyl ketone by the procedure of Example 1 gave (±)-7-tert-butyl-6-hydroxy-2-methoxy-2-methylchroman as a white solid, m.p. 115°-117° from ether-30°-60° petroleum ether.

Sources & evidence

ORD record: ord-8f2a9734feb1477dbaef0d9bfda7ee47
Source dataset: uspto-grants-1977_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04026907

Reaction notes

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