Thionyl Chloride → HCID 19382931, compound

HRID 2399638Notes

Reaction equation

[CH2:1]([O:9][C:10]1[CH:15]=[CH:14][C:13]([C:16]2[CH:21]=[CH:20][C:19]([C:22]([OH:24])=O)=[CH:18][CH:17]=2)=[CH:12][CH:11]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH:7]=[CH2:8].S(Cl)([Cl:27])=O>>[CH2:1]([O:9][C:10]1[CH:15]=[CH:14][C:13]([C:16]2[CH:21]=[CH:20][C:19]([C:22]([Cl:27])=[O:24])=[CH:18][CH:17]=2)=[CH:12][CH:11]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH:7]=[CH2:8]

Participants

Reactant 2

HCID 24386Thionyl Chloride

HCID 19382928HCID 19382928, compound

Product 1

HCID 19382931HCID 19382931, compound

Procedure

A mixture of 1.3 g of 4-(7-octenyloxy)biphenyl4'-carboxylic acid and an excessive amount of thionyl chloride was refluxed for 6 hours, and then unaltered thionyl chloride was evaporated to leave 4-(7-octenyloxy)-biphenyl-4'-carbonyl chloride.

Workup

customunaltered thionyl chloride was evaporated

Sources & evidence

ORD record: ord-96cd16a909aa4617a00776b75dfde273
Source dataset: uspto-grants-1995_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05451339

Reaction notes

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