HCID 19384516, compound → HCID 86748994, compound

HRID 2399788Notes

Reaction equation

HRID 2399788 reaction equation
C([O:3][C:4]([C:6]1[CH:7]=[CH:8][C:9]2[C:13]3[CH:14]([CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27])[CH2:15][CH2:16][C:17]([CH3:19])([CH3:18])[C:12]=3[NH:11][C:10]=2[CH:28]=1)=O)C.CC1(C)C2NC3C=C(CO)C=CC=3C=2C(CCCCCCCC)CC1>>[CH3:18][C:17]1([CH3:19])[C:12]2[NH:11][C:10]3[CH2:28][CH:6]([CH2:4][OH:3])[CH2:7][CH2:8][C:9]=3[C:13]=2[CH:14]([CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27])[CH:15]=[CH:16]1

Participants

3

Reactant 2

HCID 19384516HCID 19384516, compoundHCID 67784940HCID 67784940, compound

Product 1

HCID 86748994HCID 86748994, compound

Procedure

Using the condition described in Example 16, 4.6 g of the ethyl ester from Example 13 was reduced to 5,6,7,8-tetrahydro-6,6-dimethyl9-octyl-9H-dibenzo[b,d]pyrrole-3-methanol (3.9 g; 95%) as a yellow oil after purification on a small pad of silica gel.

Workup

  1. customafter purification on a small pad of silica gel

Sources & evidence

ORD record
ord-9297d158faab4ffaa77f095a007fbcd8
Source dataset
uspto-grants-1995_09
Patent number
US05451600

Reaction notes

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