HuagongsheHuagongshe Chemistry Print Report · For research reference only
Chloromethyl Methyl Ether → HCID 19382493, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Chloromethyl Methyl Ether | HCID 7864 | — |
| Reactant | 4-Bromoresorcinol | HCID 81105 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | HCID 19382493 | HCID 19382493 | — |
Reaction Steps
To a solution of 4-bromoresorcinol (1.5 g) in DMF (15 mL) at 0° C. was added Nail (0.19 g). After 20 min., chloromethylmethyl ether (0.636 g) was added in and stirred for 2 hrs. Saturated aq. NAHCO3 was added and the product was extracted in EtOAc, dried over Na2SO4, and purified by flash chromatography on silica gel with EtOAc in hexanes (1:6).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05453443 |
| Source dataset | uspto-grants-1995_09 |
| ORD ID | ord-ab3b1daba2e048f6974b07bda83c3383 |
| Source note | uspto-grants-1995_09 |