HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → 3-methoxy-9-oxo-9H-indeno[1,2-b]pyrazine-2-carbonitrile
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | 9-oxo-9H-indeno(1,2-b)pyrazine-2,3-dicarbonitrile | HCID 292929 | — |
| Product | 3-methoxy-9-oxo-9H-indeno[1,2-b]pyrazine-2-carbonitrile | HCID 16065353 | 126.5% |
Reaction Steps
To a suspension of 1 (1.10 g, 4.7 mmol) in MeOH (47 ml) sodium (110 mg) was added and the mixture was stirred at room temperature for 16 hours. The precipitate was filtered, washed with EtOH and dried under vacuum, yielding 3 (1.03 g, 93%) as yellow-green solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08648076B2 |
| Source dataset | uspto-grants-2014_02 |
| ORD ID | ord-b40012b19977406f87d5a10b4b6e4989 |
| Source note | uspto-grants-2014_02 |