Water → HCID 178443399, compound

HRID 2403123Notes

Reaction equation

HRID 2403123 reaction equation
[Cl-].[CH2:2]([N+:12]([CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])([CH3:14])[CH3:13])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].O.[C:26]([O-:35])(=[O:34])[C:27]1[C:28](=[CH:30][CH:31]=[CH:32][CH:33]=1)[OH:29].[Na+]>C(Cl)(Cl)Cl>[C:26]([O-:35])(=[O:34])[C:27]1[C:28](=[CH:30][CH:31]=[CH:32][CH:33]=1)[OH:29].[CH2:15]([N+:12]([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])([CH3:14])[CH3:13])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24]

Participants

5

Reactant 3

HCID 962WaterHCID 23558Didecyldimethylammonium ChlorideHCID 16760658Sodium Salicylate

Product 1

HCID 178443399HCID 178443399, compoundYield 95%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Conditions

Temperature
40 °C

Procedure

Didecyldimethylammonium chloride (0.03 mol) was dissolved in 50 mL distilled water and sodium salicylate (0.04 mol) was added to solution. The mixture was stirred at 40° C. ifor 1 h. After cooling to room temperature, 60 mL of chloroform was added. The chloroform phase was separated and washed with distilled water until chloride ions were no longer detected using AgNO3. The didecyldimethylammonium salicylate was obtained in 95% yield. The product is insoluble in water and was dried under vacuum.

Workup

  1. additionwas added to solution
  2. temperatureAfter cooling to room temperature
  3. customThe chloroform phase was separated
  4. washwashed with distilled water until chloride ions

Sources & evidence

ORD record
ord-298b6e8455d7421fa3a7c8d4cf6b1290
Source dataset
uspto-grants-2014_08
Patent number
US08802596B2

Reaction notes

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