Ammonia → HCID 178517402, compound

HRID 2404946Notes

Reaction equation

HRID 2404946 reaction equation
C([O:3][C:4]([C:6]1[C:7]2[CH:20]=[CH:19][CH:18]=[CH:17][C:8]=2[S:9][C:10]=1[NH:11][C:12]([CH:14]1[CH2:16][CH2:15]1)=O)=O)C.[NH3:21]>>[CH:14]1([C:12]2[N:21]=[C:4]([OH:3])[C:6]3[C:7]4[CH:20]=[CH:19][CH:18]=[CH:17][C:8]=4[S:9][C:10]=3[N:11]=2)[CH2:16][CH2:15]1

Participants

3

Reactant 2

HCID 222AmmoniaHCID 5201131HCID 5201131, compound

Product 1

HCID 178517402HCID 178517402, compound

Conditions

Temperature
90 °C

Procedure

A suspension of 10 millimol VII in 10 milliliter 25% aqueous NH3 was stirred at 90° C. for 24 hours in closed vial. The reaction mixture was cooled down to room temperature, and poured onto crushed ice with continuous stirring then collected by filtration. The product was washed with water and n-hexane, then dried.

Workup

  1. temperatureThe reaction mixture was cooled down to room temperature
  2. additionpoured
  3. customonto crushed ice
  4. stirringwith continuous stirring
  5. filtrationthen collected by filtration
  6. washThe product was washed with water and n-hexane
  7. customdried

Sources & evidence

ORD record
ord-93d2e80f26d1406dbdd4c1547c274560
Source dataset
uspto-grants-2014_08
Patent number
US08802849B2

Reaction notes

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