4-Iodobenzaldehyde → HCID 24961475, compound

HRID 2405541Notes

Reaction equation

HRID 2405541 reaction equation
[Br:1][C:2]1[CH:7]=[CH:6][C:5]([C:8](=[O:18])[CH2:9][S:10][C:11]2[CH:16]=[CH:15][C:14]([Br:17])=[CH:13][CH:12]=2)=[CH:4][CH:3]=1.[I:19][C:20]1[CH:27]=[CH:26][C:23]([CH:24]=O)=[CH:22][CH:21]=1>>[Br:1][C:2]1[CH:3]=[CH:4][C:5]([C:8](=[O:18])/[C:9](/[S:10][C:11]2[CH:16]=[CH:15][C:14]([Br:17])=[CH:13][CH:12]=2)=[CH:24]\[C:23]2[CH:26]=[CH:27][C:20]([I:19])=[CH:21][CH:22]=2)=[CH:6][CH:7]=1

Participants

3

Reactant 2

HCID 966574-IodobenzaldehydeHCID 43412626HCID 43412626, compound

Product 1

HCID 24961475HCID 24961475, compound

Procedure

The title compound is prepared by the methods described in Synthesis Example 1. A solution of 1-(4-bromophenyl)-2-(4-bromophenylthio)ethanone (10 mmol) and 4-iodobenzaldehyde (10 mmol) was subjected to the procedure described as Method B in part C of Synthesis Example 1 and the product obtained was purified by column chromatography. m.p. 128-130° C.

Workup

  1. customdescribed in Synthesis Example 1
  2. customdescribed as Method B in part C of Synthesis Example 1
  3. customthe product obtained
  4. customwas purified by column chromatography

Sources & evidence

ORD record
ord-344c2bf61b794e24ba1cdcc47ea1f7d7
Source dataset
uspto-grants-2014_08
Patent number
US08808702B2

Reaction notes

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