4-Iodobenzaldehyde → HCID 68539858, compound

HRID 2405547Notes

Reaction equation

HRID 2405547 reaction equation
[I:1][C:2]1[CH:7]=[CH:6][C:5]([C:8](=[O:21])[CH2:9][S:10]([CH2:13][C:14]2[CH:19]=[CH:18][C:17]([I:20])=[CH:16][CH:15]=2)(=[O:12])=[O:11])=[CH:4][CH:3]=1.[I:22][C:23]1[CH:30]=[CH:29][C:26]([CH:27]=O)=[CH:25][CH:24]=1>>[I:1][C:2]1[CH:3]=[CH:4][C:5]([C:8](=[O:21])/[C:9](/[S:10]([CH2:13][C:14]2[CH:19]=[CH:18][C:17]([I:20])=[CH:16][CH:15]=2)(=[O:11])=[O:12])=[CH:27]\[C:26]2[CH:29]=[CH:30][C:23]([I:22])=[CH:24][CH:25]=2)=[CH:6][CH:7]=1

Participants

3

Reactant 2

HCID 966574-IodobenzaldehydeHCID 68543718HCID 68543718, compound

Product 1

HCID 68539858HCID 68539858, compound

Procedure

The title compound is prepared by the methods described in Synthesis Example 10. A solution of 1-(4-iodophenyl)-2-(4-iodobenzylsulfonyl)ethanone (10 mmol) and 4-iodobenzaldehyde (10 mmol) was subjected to the procedure described as Method A in part C of Synthesis Example 10 and the product obtained was purified by column chromatography.

Workup

  1. customdescribed in Synthesis Example 10
  2. customdescribed as Method A in part C of Synthesis Example 10
  3. customthe product obtained
  4. customwas purified by column chromatography

Sources & evidence

ORD record
ord-5693be8ee7b045e5962ebcc84560209c
Source dataset
uspto-grants-2014_08
Patent number
US08808702B2

Reaction notes

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