1,1,1-Trifluoro-2-methylpropan-2-ol → Sulfamic acid 2,2,2-trifluoro-1,1-dimethyl-ethyl ester

HRID 2405791Notes

Reaction equation

HRID 2405791 reaction equation
C1([O:7][S:8](=O)(=[O:10])[NH2:9])C=CC=CC=1.[F:12][C:13]([F:19])([F:18])[C:14]([CH3:17])([OH:16])[CH3:15]>>[F:12][C:13]([F:19])([F:18])[C:14]([O:16][S:8](=[O:10])(=[O:7])[NH2:9])([CH3:17])[CH3:15]

Participants

3

Reactant 2

HCID 681821,1,1-Trifluoro-2-methylpropan-2-olHCID 11030308Phenylsulfamate

Product 1

HCID 57785083Sulfamic acid 2,2,2-trifluoro-1,1-dimethyl-ethyl ester

Procedure

Sulfamic acid 2,2,2-trifluoro-1,1-dimethyl-ethyl ester was synthesized according to the method presented in the synthesis of sulfamic acid phenyl ester in Example 1 with the exception of utilizing 1,1,1-trifluoro-2-methyl-propan-2-ol to obtain sulfamic acid 2,2,2-trifluoro-1,1-dimethyl-ethyl ester.

Workup

  1. customSulfamic acid 2,2,2-trifluoro-1,1-dimethyl-ethyl ester was synthesized

Sources & evidence

ORD record
ord-9410f759643447bf8b075aff6909085f
Source dataset
uspto-grants-2014_08
Patent number
US08809267B2

Reaction notes

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