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HRID2406601

反应详情

EQUATION

反应方程式

HRID 2406601 的结构方程式

REACTANTS

反应物

2
结构：CCCC(NC(=O)/C=C/c1cccc(Br)n1)c1ccc(OCCOCCOCCN(C(=O)OC(C)(C)C)C(=O)OC(C)(C)C)cc1
HCID86762605

未命名化合物

结构：CCCC(NC(=O)/C(C#N)=C/c1cccc(Br)n1)c1ccc(OCCOCCOCCNC(=O)CCCC[C@@H]2SC[C@@H]3NC(=O)N[C@@H]32)cc1
HCID87168264

未命名化合物

PRODUCTS

生成物

1
结构：CCCC(NC(=O)/C=C/c1cccc(Br)n1)c1ccc(OCCOCCOCCNC(=O)CCCC[C@@H]2SC[C@@H]3NC(=O)N[C@@H]32)cc1
HCID87168521

未命名化合物

PROCEDURE

实验过程

The title compound was prepared by using a similar procedure as described for the preparation of 48 except that acrylamide 50 was used instead of cyanoacrylamide 47. This produced the crude product which was purified by flash silica gel column chromatography, eluting with 7:93 methanol/dichloromethane, to give 51 (50 mg, quantitative) as a clear oil: MS (ES+) m/z 731.2 (M+H)+.

WORKUP

后处理

  1. customThis produced the crude product which