関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Benzyl azide | HCID 12152 | — |
| 反応物 | Tributyl(prop-1-yn-1-yl)stannane | HCID 2733165 | — |
| 生成物 | 1-Benzyl-5-methyl-4-(tributylstannyl)-1H-1,2,3-triazole | HCID 68990342 | — |
反応手順
Tributyl(1-propynyl)tin (3.87 g, 11.8 mmol) and benzyl azide (2.2 mL, 17.6 mmol) were combined and heated to 150° C. overnight. The mixture was purified by silica gel chromatography eluting with a gradient of 5-40% ethyl acetate in hexanes to afford the title compound. MS (ESI+) m/z 464.2 (M+H)+.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US08648069B2 |
|---|
| 出典データセット | uspto-grants-2014_02 |
|---|
| ORD ID | ord-b4ca326d8b7d43b6a5b90edc7a946609 |
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| 出典メモ | uspto-grants-2014_02 |
|---|
