HuagongsheHuagongshe Chemistry Print Report · For research reference only
Chloroacetonitrile → 3-Amino-5-phenylselenophene-2-carbonitrile
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Chloroacetonitrile | HCID 7856 | — |
| Reactant | Sodium selenide | HCID 73973 | — |
| Reactant | 3-Chloro-3-phenyl-2-propenenitrile | HCID 2777511 | — |
| Product | 3-Amino-5-phenylselenophene-2-carbonitrile | HCID 86646888 | 53% |
Reaction Steps
The reaction of 3-chloro-3-phenylprop-2-enenitrile, sodium selenide and chloroacetonitrile as described earlier gave the product as a brown color solid (4.8 g, 53%), mp 162-164° C. (decomp). 1H NMR (400 MHz, CDCl3): δ 7.46-7.49 (2H, m), 7.37-7.39 (3H, m), 7.01 (1H, s), 4.55 (2H, br s).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08815879B2 |
| Source dataset | uspto-grants-2014_08 |
| ORD ID | ord-9478aa3fdc764589bb16a3f3187981d6 |
| Source note | uspto-grants-2014_08 |