Methyl Acetate → HCID 11075009, compound

HRID 2409114Notes

Reaction equation

[N+:1]([C:4]1[CH:5]=[C:6](/[C:10](=N/[S@@](C(C)(C)C)=O)/[CH3:11])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2].[C:19]([O:22][CH3:23])(=[O:21])[CH3:20]>>[CH3:23][O:22][C:19](=[O:21])[CH2:20][CH:10]([C:6]1[CH:7]=[CH:8][CH:9]=[C:4]([N+:1]([O-:3])=[O:2])[CH:5]=1)[CH3:11]

Participants

Reactant 2

HCID 6584Methyl Acetate

HCID 87126834HCID 87126834, compound

Product 1

HCID 11075009HCID 11075009, compound

Procedure

Starting from (R)-2-methyl-propane-2-sulfinic acid [1-(3-nitro-phenyl)-(E)-ethylidene]-amide and methyl acetate, the product (S)-3-(R)-2-methyl-propane-2-sulfinylamino)-3-(3-nitro-phenyl)-butyric acid methyl ester was obtained as a pale yellow oil. MS (ESI): m/z=343.1 [M+H]+.

Sources & evidence

ORD record: ord-75a4843688f344a4835c1d803d31cd94
Source dataset: uspto-grants-2014_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08815881B2

Reaction notes

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