Methyl Acetate → HCID 86661856, compound

HRID 2409115Notes

Reaction equation

[N+:1]([C:4]1[CH:5]=[CH:6][CH:7]=[C:8](/[C:10](=N/[S@@](C(C)(C)C)=O)/[CH2:11][CH2:12][CH3:13])[CH:9]=1)([O-:3])=[O:2].[C:21]([O:24][CH3:25])(=[O:23])[CH3:22]>>[CH3:25][O:24][C:21](=[O:23])[CH2:22][CH:10]([C:8]1[CH:7]=[CH:6][CH:5]=[C:4]([N+:1]([O-:3])=[O:2])[CH:9]=1)[CH2:11][CH2:12][CH3:13]

Participants

Reactant 2

HCID 6584Methyl Acetate

HCID 178449959HCID 178449959, compound

Product 1

HCID 86661856HCID 86661856, compound

Procedure

Starting from (R)-2-methyl-propane-2-sulfinic acid [1-(5-nitro-phenyl)-(E)-butylidene]-amide and methyl acetate, the product (S)-3-(R)-2-methyl-propane-2-sulfinylamino)-3-(3-nitro-phenyl)-hexanoic acid methyl ester was obtained as a white solid. MS (ESI): m/z=371.4 [M+H]+.

Sources & evidence

ORD record: ord-8266bd68ac1940d5a9ecf0820a156be8
Source dataset: uspto-grants-2014_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08815881B2

Reaction notes

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