Methyl Acetate → HCID 66727740, compound

HRID 2409116Notes

Reaction equation

[N+:1]([C:4]1[CH:12]=[C:11]2[C:7]([CH2:8][CH2:9]/[C:10]/2=[N:13]\[S:14]([C:16]([CH3:19])([CH3:18])[CH3:17])=[O:15])=[CH:6][CH:5]=1)([O-:3])=[O:2].[C:20]([O:23][CH3:24])(=[O:22])[CH3:21]>>[CH3:24][O:23][C:20](=[O:22])[CH2:21][C@:10]1([NH:13][S@@:14]([C:16]([CH3:19])([CH3:18])[CH3:17])=[O:15])[C:11]2[C:7](=[CH:6][CH:5]=[C:4]([N+:1]([O-:3])=[O:2])[CH:12]=2)[CH2:8][CH2:9]1

Participants

Reactant 2

HCID 6584Methyl Acetate

HCID 58082880HCID 58082880, compound

Product 1

HCID 66727740HCID 66727740, compound

Procedure

Starting from 2-methyl-propane-2-sulfinic acid [6-nitro-indan-(1E)-ylidene]-amide and methyl acetate, the product [(S)-1-((R)-2-methyl-propane-2-sulfinylamino)-6-nitro-indan-1-yl]-acetic acid methyl ester was obtained as a black oil. MS (ESI): m/z=355.5 [M+H]+.

Sources & evidence

ORD record: ord-aa8ca5b57d814fccb3041c6148a4dd5b
Source dataset: uspto-grants-2014_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08815881B2

Reaction notes

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