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Dimethylamine → Dimethyl(dimethylamino)ethoxysilane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Dimethylamine | HCID 674 | — |
| 反応物 | Tetrahydrofuran | HCID 8028 | — |
| 反応物 | Bis(dimethylamino)dimethylsilane | HCID 77384 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | Dimethyl(dimethylamino)ethoxysilane | HCID 102480692 | — |
反応手順
A 2 L 3 neck flask equipped with a magnetic stirrer, Frederich's condensor and an addition funnel was charged with 361 mls of bis(dimethylamino)dimethylsilane and an equal volume of tetrahydrofuran. At ambient temperature, 116 mls of anhydrous ethanol was added over one hour. Dimethylamine evolved. The mixture was transferred to a single neck flask and distilled. 264 g of dimethyl(dimethylamino)ethoxysilane, (b.p. 115°-118° C.), was recovered.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04491669 |
| 出典データセット | uspto-grants-1985_01 |
| ORD ID | ord-8d8c2afd79424dc693355cf7c621ac61 |
| 出典メモ | uspto-grants-1985_01 |