HuagongsheHuagongshe Chemistry Print Report · For research reference only
Aniline → 6-(Phenylamino)-5,8-quinolinedione
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Aniline | HCID 6115 | — |
| Reactant | Cerium(III) chloride | HCID 24636 | — |
| Reactant | 5,8-Dihydroquinoline-5,8-dione | HCID 388306 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 6-(Phenylamino)-5,8-quinolinedione | HCID 3976 | — |
Reaction Steps
Twenty and one-half grams of quinoline-5,8-quinone were dissolved in 500 ml of absolute ethanol, then 13 g of aniline were added, followed by the addition of 32 g of cerium chloride. This reaction mixture was refluxed overnight. The resulting mixture had a brown-blue color and was stirred and then left to cool to room temperature for about 26 hours.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04492704 |
| Source dataset | uspto-grants-1985_01 |
| ORD ID | ord-0282439f41104f159b40942a981c5397 |
| Source note | uspto-grants-1985_01 |