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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2412807Generated: November 3, 2026

Benzaldehyde → 1,1-Diphenylethylene

https://huagongshe.com/reaction/2412807

Reaction equation

Participants

RoleNameHCIDCharge
ReactantBenzaldehydeHCID 240—
ReactantBenzophenoneHCID 3102—
Reactant1,2-Diphenyl-1-propeneHCID 13070—
ReactantSodium borohydrideHCID 4311764—
Reactant2-(1-Phenylethyl)benzaldehydeHCID 12535348—
ReactantHCID 178418373HCID 178418373—
ReactantHCID 178419663HCID 178419663—
Product1,1-DiphenylethyleneHCID 10740—
ProductStilbeneHCID 11502—
ProductPhenyl(isopropenylphenyl)ethaneHCID 20069234—

Reaction Steps

For instance, vinylnaphthalene is prepared by reacting formylnaphthalene with a Grignard reagent such as methylmagnesium iodide, and then dehydrating. Phenyl(vinylphenyl)ethane is prepared by reacting diphenylethane with acetyl chloride in the presence of a Friedel-Crafts catalyst to obtain phenyl(acetylphenyl)ethane, reducing by sodium borohydride, and then dehydrating. Phenyl(isopropenylphenyl)ethane is prepared by reacting phenyl(formylphenyl)ethane with a Grignard reagent such as methylmagnesium iodide, and then dehydrating. 1,2-Diphenylethylene is prepared by reacting benzaldehyde with benzylmagnesium bromide, and then dehydrating. 1,2-Diphenylpropene is also prepared by a similar method. 1,1-Diphenylethylene is prepared by reacting diphenyl ketone with a Grignard reagent such as methylmagnesium iodide, and then dehydrating.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS04493943
Source datasetuspto-grants-1985_01
ORD IDord-63d840fcdc7c4fffacb02ca464cedc3f
Source noteuspto-grants-1985_01