3,4-Dichloroaniline → 3,4-Dichloroaniline

HRID 2413051Notes

Reaction equation

HRID 2413051 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([CH:6]=[C:7](Cl)[C:8]=1Cl)[NH2:5].[Cl:11][C:12]1[CH:13]=[C:14]([CH:16]=[CH:17][C:18]=1[Cl:19])[NH2:15]>>[Cl:1][C:2]1[CH:3]=[C:4]([CH:6]=[CH:7][CH:8]=1)[NH2:5].[Cl:11][C:12]1[CH:13]=[C:14]([CH:16]=[CH:17][C:18]=1[Cl:19])[NH2:15]

Participants

4

Reactant 2

HCID 72573,4-DichloroanilineHCID 124693,4,5-Trichloroaniline

Product 2

HCID 72573,4-DichloroanilineYield 100%HCID 79323-Chloroaniline

Procedure

Example 9 is repeated, the 3,4,5-trichloroaniline being replaced by 3,4-dichloroaniline. After a reaction time of 7 hours under the same conditions, 3-chloroaniline is obtained with a yield of 100% for a degree of conversion of 100% of the 3,4-dichloroaniline. The degree of hydrodechlorination of the solvent is 0.09%.

Sources & evidence

ORD record
ord-5f0258afdf7d4331aa2c92a6f1268f6b
Source dataset
uspto-grants-1985_01
Patent number
US04495368

Reaction notes

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