HCID 13371473, compound → HCID 13371474, compound

HRID 2413277Notes

Reaction equation

HRID 2413277 reaction equation
C([O:8][C:9]1[CH:14]=[CH:13][C:12]([NH:15][C:16]2[CH:21]=[CH:20][C:19]([O:22][CH3:23])=[CH:18][C:17]=2[C:24](=[O:26])[CH3:25])=[CH:11][CH:10]=1)C1C=CC=CC=1>C(Cl)(Cl)Cl>[OH:8][C:9]1[CH:10]=[CH:11][C:12]([NH:15][C:16]2[CH:21]=[CH:20][C:19]([O:22][CH3:23])=[CH:18][C:17]=2[C:24](=[O:26])[CH3:25])=[CH:13][CH:14]=1

Participants

3

Reactant 1

HCID 13371473HCID 13371473, compound

Product 1

HCID 13371474HCID 13371474, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

1-[2-(4-Hydroxyphenylamino)-5-methoxyphenyl]ethanone [XIV; R=5-CH3O, R"=H, OH at 4-position] was prepared by hydrogenation of 1-[2-(4-benzyloxyphenylamino)-5-methoxyphenyl]ethanone according to the procedure of Example 5, part (b), and obtained in the form of an orange powder, m.p. 118°-119° C. after chromatography on silica gel with chloroform eluant.

Sources & evidence

ORD record
ord-561aec158ccc4d03808af5da1dd47700
Source dataset
uspto-grants-1985_01
Patent number
US04496590

Reaction notes

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