(10-Bromo-1-anthracenyl)methanol → HCID 14370037, compound

HRID 2413615Notes

Reaction equation

HRID 2413615 reaction equation
[Br:1][C:2]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH:9]=[C:8]2[C:3]=1[CH:4]=[CH:5][CH:6]=[C:7]2[CH2:16][OH:17].C1C=C[NH+]=CC=1.[O-][Cr](Cl)(=O)=O>>[Br:1][C:2]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH:9]=[C:8]2[C:3]=1[CH:4]=[CH:5][CH:6]=[C:7]2[CH:16]=[O:17]

Participants

3

Reactant 2

HCID 13375398(10-Bromo-1-anthracenyl)methanolHCID 178418287HCID 178418287, compound

Product 1

HCID 14370037HCID 14370037, compound

Procedure

Using the procedure outlined in 2D, oxidation of (10-bromo-1-anthryl)methanol with PCC gave 10-bromo-1-anthracenecarbaldehyde mp 134.5°-135.5°, (PhCH3 /hexane), (C,H,Br).

Sources & evidence

ORD record
ord-1d27ad63438a45ad8fdd35e7409cdc67
Source dataset
uspto-grants-1988_01
Patent number
US04719047

Reaction notes

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