Anthracenecarboxaldehyde → HCID 14370037, compound

HRID 2413643Notes

Reaction equation

HRID 2413643 reaction equation
C1(C=O)C2C(=CC3C(C=2)=CC=CC=3)C=CC=1.[Br:17][C:18]1[C:31]2[C:26](=[CH:27][CH:28]=[CH:29][CH:30]=2)[CH:25]=[C:24]2[C:19]=1[CH:20]=[CH:21][CH:22]=[C:23]2[CH2:32][OH:33].[Cr](Cl)([O-])(=O)=O.[NH+]1C=CC=CC=1>>[Br:17][C:18]1[C:31]2[C:26](=[CH:27][CH:28]=[CH:29][CH:30]=2)[CH:25]=[C:24]2[C:19]=1[CH:20]=[CH:21][CH:22]=[C:23]2[CH:32]=[O:33]

Participants

4

Reactant 3

HCID 35864AnthracenecarboxaldehydeHCID 13375398(10-Bromo-1-anthracenyl)methanolHCID 178418287HCID 178418287, compound

Product 1

HCID 14370037HCID 14370037, compound

Procedure

Using the procedure outlined in 15D, oxidation of (10-bromo-1-anthracenyl)methanol (16A) with pyridinium chlorochromate (Aldrich) gave 10-bromo-1-anthracenecarbaldehyde mp 134.5°-135.5°, (PhCH3 /hexane), (C, H, Br).

Sources & evidence

ORD record
ord-497214ed48684c5baf4063e26d8a640c
Source dataset
uspto-grants-1988_01
Patent number
US04719049

Reaction notes

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