HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → HCID 20155094, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | Acetohydrazide | HCID 14039 | — |
| Reactant | 9-ETHYL-3-ISOTHIOCYANATO-9H-CARBAZOLE | HCID 5018372 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 20155094 | HCID 20155094 | — |
Reaction Steps
3.8 g of 9-ethyl-3-isothiocyanatocarbazole was reacted with 1.1 g of acetylhydrazine in 30 ml of tetrahydrofuran at 60° C. for 2 hours. Then, 10 ml of methanol was added thereto and crystallization was conducted while cooling with ice. Crystals thus precipitated were collected by filtration, and recrystallized from CHCl3 /CH3OH (70 ml/200 ml) to obtain 2.4 g of the desired end compound. m.p. 197°-199° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04719174 |
| Source dataset | uspto-grants-1988_01 |
| ORD ID | ord-d5f80df6338b4a4abf6434ca472af9ef |
| Source note | uspto-grants-1988_01 |