2,2,2-Trifluoro-n-octylacetamide → N-Dodecyl-Perfluoroalkanamide

HRID 2413843Notes

Reaction equation

HRID 2413843 reaction equation
C(NC(=O)C(F)(F)F)CC.C(NC(=O)C(F)(F)F)CCCC.C(NC(=O)C(F)(F)F)CCCCCCC.C(NC(=O)C(F)(F)F)CCCCCCCCC.[CH2:55]([NH:71][C:72](=[O:77])[C:73]([F:76])([F:75])[F:74])[CH2:56][CH2:57][CH2:58][CH2:59][CH2:60][CH2:61][CH2:62][CH2:63][CH2:64][CH2:65][CH2:66]CCCC.C(NC(=O)C(F)(F)F)CCCCCCCCCCCCCCCCC>>[CH2:55]([NH:71][C:72](=[O:77])[C:73]([F:75])([F:76])[F:74])[CH2:56][CH2:57][CH2:58][CH2:59][CH2:60][CH2:61][CH2:62][CH2:63][CH2:64][CH2:65][CH3:66]

Participants

7

Reactant 6

HCID 5352842,2,2-Trifluoro-n-octylacetamideHCID 540859HCID 540859, compoundHCID 5809202,2,2-Trifluoro-n-pentylacetamideHCID 580996Acetamide, 2,2,2-trifluoro-N-propyl-HCID 603428Acetamide, N-decyl-2,2,2-trifluoro-HCID 4674726HCID 4674726, compound

Product 1

HCID 611266N-Dodecyl-Perfluoroalkanamide

Procedure

The following similar compounds were all prepared in the same manner, all with similar NMR, acceptable microanalyses, mass spectra, and single spot on TLC: N-propyl-trifluoroacetamide, N-pentyl-trifluoroacetamide, N-octyl-trifluoroacetamide, N-decyl-trifluoroacetamide, N-hexadecyl-trifluoroacetamide, N-octadecyl-trifluoroacetamide.

Workup

  1. customall prepared in the same manner

Sources & evidence

ORD record
ord-55125fd10dd64212b33d4c578278f654
Source dataset
uspto-grants-1988_01
Patent number
US04719312

Reaction notes

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