HRID2413980

反应详情

EQUATION

反应方程式

HRID 2413980 的结构方程式

REACTANTS

反应物

2

结构：CC(C)=O

Acetone

C3H6O

结构：CO[C@@]12[C@H](COC(N)=O)C3=C(C(=O)C(C)=C(N)C3=O)N1C[C@@H]1N[C@@H]12

Mitomycin C

C15H18N4O5

PRODUCTS

生成物

1

结构：COC1=C(C)C(=O)C2=C(C1=O)[C@@H](COC(N)=O)[C@@]1(OC)[C@H]3N[C@H]3CN21

Mitomycin A

C16H19N3O6

AUXILIARIES

试剂、催化剂与溶剂

1

结构：CO

Methanol

CH4O

PROCEDURE

实验过程

TLC (ETOAC:Acetone) one spot Rf =0.91; UV (MeOH) 216 and 358 mu NMR(CDCl3); appearance of singlet at 4.04 corresponding to the 7-methoxy group which is not present in the parent compound mitomycin C.