Formic Acid → HCID 86690523, compound

HRID 241495Notes

Reaction equation

HRID 241495 reaction equation
[C:1]([C:5]1[CH:10]=[CH:9][C:8]([C:11]#[CH:12])=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2].[CH:13]([OH:15])=O>>[C:1]([C:5]1[CH:6]=[CH:7][C:8]([C:11]#[C:12][CH:13]([OH:15])[C:12]#[C:11][C:8]2[CH:7]=[CH:6][C:5]([C:1]([CH3:4])([CH3:3])[CH3:2])=[CH:10][CH:9]=2)=[CH:9][CH:10]=1)([CH3:4])([CH3:3])[CH3:2]

Participants

3

Procedure

In the first stage, (A) 4-tert-butylphenylacetylene, organic magnesium halide, and a formic acid derivative are used, thereby obtaining (B) 1,5-bis(4-tert-butylphenyl)-penta-1,4-diyn-3-ol.

Sources & evidence

ORD record
ord-10d957c0ae9a4f8cbc25c47877340429
Source dataset
uspto-grants-2014_02
Patent number
US08652718B2

Reaction notes

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