HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrogen Peroxide → 4,7-Dichloroquinoline 1-oxide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrogen Peroxide | HCID 784 | — |
| Reactant | 4,7-Dichloroquinoline | HCID 6866 | — |
| Catalyst | HCID 178477782 | HCID 178477782 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 4,7-Dichloroquinoline 1-oxide | HCID 280096 | — |
Reaction Steps
A mixture of 4,7-dichloroquinoline (9.9 g, 50 mmol) and methyltrioxorhenium (80 mg, 0.32 mmol) was stirred in the mixture of hydrogenperoxide (40%, 20 mL) and dichloromethane at room temperature for 24 hours. Pale yellow solid was collected by filtration and dried under vacuum. MS (ESI(+)Q1MS m/z 215 (M+H)+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06818772B2 |
| Source dataset | uspto-grants-2004_11 |
| ORD ID | ord-e3258ff6faf74080801c127d4b5bf9d7 |
| Source note | uspto-grants-2004_11 |