HuagongsheHuagongshe Chemistry Print Report · For research reference only
2,2',7,7'-tetrabromo-9,9'-spirobifluorene → 9,9'-Spirobi[fluorene]-2,2'-dicarboxylic acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2,2',7,7'-tetrabromo-9,9'-spirobifluorene | HCID 371282 | — |
| Reactant | HCID 15375393 | HCID 15375393 | — |
| Reactant | HCID 22016039 | HCID 22016039 | — |
| Reactant | HCID 22016054 | HCID 22016054 | — |
| Reactant | HCID 22016059 | HCID 22016059 | — |
| Reactant | HCID 22638508 | HCID 22638508 | — |
| Product | 9,9'-Spirobi[fluorene]-2,2'-dicarboxylic acid | HCID 5259981 | — |
Reaction Steps
i-k) 9,9′-Spirobifluorene-2,2′,7,7′-tetracarboxylic acid can be prepared in an analogous way from 2,2′,7,7′-tetrabromo-9,9′-spirobifluorene; likewise, 9,9′-spirobifluorene-2,2′,7-tricarboxylic acid can be prepared from 2,2′,7-tribromo-9,9′-spirobifluorene and 9,9′-spirobifluorene-2,2′,4,4′,7,7′-hexacarboxylic acid can be prepared from 2,2′,4,4′,7,7′-hexabromo-9,9′-spirobifluorene by analogous methods.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06822094B2 |
| Source dataset | uspto-grants-2004_11 |
| ORD ID | ord-30bf60dc7bc846dda65d74c607e0b80b |
| Source note | uspto-grants-2004_11 |