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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2416290Generated: November 1, 2026

2,2',7,7'-tetrabromo-9,9'-spirobifluorene → 9,9'-Spirobi[fluorene]-2,2'-dicarboxylic acid

https://huagongshe.com/reaction/2416290

Reaction equation

Participants

RoleNameHCIDCharge
Reactant2,2',7,7'-tetrabromo-9,9'-spirobifluoreneHCID 371282—
ReactantHCID 15375393HCID 15375393—
ReactantHCID 22016039HCID 22016039—
ReactantHCID 22016054HCID 22016054—
ReactantHCID 22016059HCID 22016059—
ReactantHCID 22638508HCID 22638508—
Product9,9'-Spirobi[fluorene]-2,2'-dicarboxylic acidHCID 5259981—

Reaction Steps

i-k) 9,9′-Spirobifluorene-2,2′,7,7′-tetracarboxylic acid can be prepared in an analogous way from 2,2′,7,7′-tetrabromo-9,9′-spirobifluorene; likewise, 9,9′-spirobifluorene-2,2′,7-tricarboxylic acid can be prepared from 2,2′,7-tribromo-9,9′-spirobifluorene and 9,9′-spirobifluorene-2,2′,4,4′,7,7′-hexacarboxylic acid can be prepared from 2,2′,4,4′,7,7′-hexabromo-9,9′-spirobifluorene by analogous methods.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS06822094B2
Source datasetuspto-grants-2004_11
ORD IDord-30bf60dc7bc846dda65d74c607e0b80b
Source noteuspto-grants-2004_11