4-Mercaptophenol → HCID 90750084, compound

HRID 2417280Notes

Reaction equation

Br[CH:2]([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1[O:14][CH3:15])[C:3]([O:5][CH2:6][CH3:7])=[O:4].[SH:16][C:17]1[CH:22]=[CH:21][C:20]([OH:23])=[CH:19][CH:18]=1>>[CH2:6]([O:5][C:3](=[O:4])[CH:2]([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1[O:14][CH3:15])[S:16][C:17]1[CH:22]=[CH:21][C:20]([OH:23])=[CH:19][CH:18]=1)[CH3:7]

Participants

Reactant 2

HCID 2401474-Mercaptophenol

HCID 19385641HCID 19385641, compound

Product 1

HCID 90750084HCID 90750084, compoundYield 89%

Procedure

Ethyl(2-methoxyphenyl)[(4-hydroxyphenyl)sulfanyl]acetate was prepared according to the general method as outlined in example 1 (step 1), starting from ethyl bromo(2-methoxyphenyl)acetate (24 g, 87.5 mmol) and 4-mercaptophenol (11.0 g, 87.5 mmol); 24.9 g amber colored oil. Yield 89%; MS: 320 (M+H)+

Sources & evidence

ORD record: ord-c5cf0bc428874ea98a27d34698a642fe
Source dataset: uspto-grants-2004_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06825354B2

Reaction notes

Loading…