Iron(2+) tetrafluoroborate--water (1/2/6) → Iron(II) tetrafluoroborate

HRID 2417300Notes

Reaction equation

HRID 2417300 reaction equation
O.O.O.O.O.O.[F:7][B-:8]([F:11])([F:10])[F:9].[F:12][B-:13]([F:16])([F:15])[F:14].[Fe+2:17]>ClCCl>[F:7][B-:8]([F:11])([F:10])[F:9].[F:12][B-:13]([F:16])([F:15])[F:14].[Fe+2:17]

Participants

3

Reactant 1

HCID 15762351Iron(2+) tetrafluoroborate--water (1/2/6)

Product 1

HCID 11736352Iron(II) tetrafluoroborate

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent2×

Procedure

To a suspension of iron(II) bis(tetrafluoroborate)hexahydrate (4.9 mg; 15 μmol) in dichloromethane was added a solution of h17 (5.0 mg; 14 μmol) in a few milliliters of dichloromethane. The solution turned from light yellow to dark orange with time within 18 hours. The solution was used as is in further polymerization study.

Workup

  1. customwithin 18 hours

Sources & evidence

ORD record
ord-f952c70f2fbe46af861191f886200573
Source dataset
uspto-grants-2004_11
Patent number
US06825356B2

Reaction notes

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