Ethylene → Iron(II) tetrafluoroborate

HRID 2417301Notes

Reaction equation

HRID 2417301 reaction equation
O.O.O.O.O.O.[F:7][B-:8]([F:11])([F:10])[F:9].[F:12][B-:13]([F:16])([F:15])[F:14].[Fe+2:17].C=C>ClCCl>[F:7][B-:8]([F:11])([F:10])[F:9].[F:12][B-:13]([F:16])([F:15])[F:14].[Fe+2:17]

Participants

4

Reactant 2

HCID 6325EthyleneHCID 15762351Iron(2+) tetrafluoroborate--water (1/2/6)

Product 1

HCID 11736352Iron(II) tetrafluoroborate

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent2×

Procedure

A solution of h25 (5.1 mg; 8.9 μmol) in about 2 mL dichloromethane was added to a suspension of iron bis(tetrafluoroborate)hexahydrate (3.0 mg; 8.9 μmol) in dichloromethane. The mixture was stirred at room temperature for about 18 hours before being used in the polymerization of Ethylene.

Sources & evidence

ORD record
ord-29fff66fb212407291d4fb516e8816b5
Source dataset
uspto-grants-2004_11
Patent number
US06825356B2

Reaction notes

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