Boronic Acid → HCID 22634681, compound

HRID 2417334Notes

Reaction equation

HRID 2417334 reaction equation
Br[C:2]1[C:3]([O:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23])=[CH:4][C:5]2[C:6]([CH3:15])([CH3:14])[CH2:7][CH2:8][C:9]([CH3:13])([CH3:12])[C:10]=2[CH:11]=1.[BH:24]([OH:26])[OH:25]>>[CH2:17]([O:16][C:3]1[CH:2]=[CH:11][C:10]2[C:9]([CH3:13])([CH3:12])[CH2:8][CH2:7][C:6]([CH3:15])([CH3:14])[C:5]=2[C:4]=1[B:24]([OH:26])[OH:25])[CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23]

Participants

3

Reactant 2

HCID 61668Boronic AcidHCID 22634676HCID 22634676, compound

Product 1

HCID 22634681HCID 22634681, compound

Procedure

In a similar manner to Example 3(a), starting with 10 g (26.2 mmol) of 3-bromo-2-heptyloxy-5,6,7,8-tetrahydro-5,5,8,8-tetramethylnaphthalene, 6.1 g (67%) of the expected boronic acid are obtained, with a melting point of 102-3° C.

Workup

  1. customare obtained, with a melting point of 102-3° C.

Sources & evidence

ORD record
ord-f16433ae2ddc4bf2a660c594e01202fb
Source dataset
uspto-grants-2004_11
Patent number
US06825360B1

Reaction notes

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